Reprints/Updates of this OSHA MSDS are available at our website, WWW.CIMCOOL.COM.

MATERIAL SAFETY DATA SHEET

ADDITIVE 90

METALWORKING FLUID ADDITIVE

MSDS: 564

FS: 15-Aug-01: 9671: 1674

DATE EFFECTIVE: 8/15/01

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Manufacturer:

Consumable Products Division

Milacron Marketing Company

3000 Disney Street

Cincinnati, Ohio 45209

Emergency Telephone Number: 1-800-447-6130

Information Telephone Number: 1-513-458-8199

Generic Name: Water Soluble Metalworking Fluid Additive

Product Name(s) & Code(s): ADDITIVE 90 UNDYED 564;

2. EMERGENCY INFORMATION

Product is combustible. Highway spills could result in slippery conditions. No other significant health effects are associated with this material.

3. POTENTIAL HEALTH EFFECTS OF DIRECT EXPOSURE

 

Product Concentrate

Product at Use Dilution

Inhalation

Not Applicable.

Extended Exposure to mists may cause upper respiratory irritation.

Eye Contact

Product is not a primary eye irritant.

Will cause stinging sensation in the eye.

Skin Contact

Product is not a primary skin irritant.

Not irritating to the skin when used as directed and good personal hygiene is practiced.

Ingestion

Not orally toxic.

Swallowing small quantities may cause nausea or diarrhea.

When used in applications generating high levels of mist, operator exposure can be minimized by proper ventilation, use of mist collectors or splash guards, as appropriate. If there is doubt about actual mist levels present, monitoring should be conducted.

Mild skin irritation (redness and dryness of hands) may be experienced when the diluted product has been contaminated by certain oils by dissolved metals, or when mix ratio is too strong. When problems occur, use of water-resistant barrier creams may be a temporary control measure. Contact CIMCOOL® Technical Services at 1-513-458-8199 for specific recommendations.

 

 

Carcinogen Listings

NTP: No

IARC: No

OSHA: No

Signs and symptoms of exposure: Eye injury may result from contact with concentrated product. Skin irritation can result from improper use and handling of concentrate or mix.

Medical conditions generally aggravated by exposure: May aggravate existing skin irritation where further defatting or skin penetration could occur.

4. EMERGENCY AND FIRST AID PROCEDURES

Eyes: In case of eye contact with concentrated product or diluted mix, flush immediately with running water for 15 minutes, then promptly get medical attention to check for possible irritation.

Skin contact: In case of skin contact with product concentrate, wash with water as soon as possible.

Diluted product is not irritating to the skin when used as recommended and good personal hygiene is practiced. Remove severely contaminated clothing, including shoes. Launder before reuse. If irritation persists, get medical attention.

Ingestion: If concentrate or mix is swallowed, do not induce vomiting. Dilute by drinking water or milk. Immediately contact physician and obtain treatment. Swallowing small quantities of diluted product is not expected to cause injury or illness; but, as should be expected when drinking oily, soapy water, nausea, diarrhea or abdominal distress may be experienced.

Inhalation: Not expected to be a probable route of exposure to product concentrate. Inhalation of diluted mix can occur in applications where high mist levels are generated. OSHA has set a PEL of 15 mg/M3 for any airborne particulate as a nuisance level of exposure. NIOSH has set a REL of 0.5 mg/M3 for metalworking fluid mist.

5. CONTROL MEASURES

Respiratory Protection: Product concentrate is not volatile. No misting would be expected when handling product concentrate.

In applications where time-weighted exposures are 0.5 to 5 mg/m3, mist reduction through improved ventilation, mist collection or process modification is recommended by NIOSH. Where this is not possible, NIOSH recommends the use of any air purifying, half-mask respirator including a disposable respirator, equipped with any P- or R-series particulate filter. If the average exposure will exceed 5 mg/m3, NIOSH recommends use of a powered, air-purifying respirator equipped with a hood or helmet and a HEPA filter. If respiratory problems are present when mist levels are < 0.5 mg/m3, respiratory protection should be based on the individual recommendation of a qualified health care provider.

Caution: The appropriate use and type of respirator is dependent upon use of the product and local operating conditions.

Ventilation: For most applications, normal shop ventilation is adequate. However, when high mist levels are generated or where machines are close together or ventilation is inadequate, operators may experience respiratory irritation. For such applications, use of splash guards or mist collectors is recommended.

Eye Protection: Safety shield or goggles required when handling concentrated product.

Other protective clothing or equipment: Effective metalworking plant protective clothing as appropriate.

Work/Hygiene Practices: Good personal hygiene should always be followed.

Protective Gloves: Impervious gloves, such as nitrile gloves, are recommended when handling product concentrate.

6. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

This product has been determined to be non-hazardous in accordance with 29 CFR 1900.1200(d) (hazard determination).

7. FIRE AND EXPLOSION HAZARD DATA

Flash Point (COC): 380oF

Flammable Limits:

Lower Explosive Limit: NA

Upper Explosive Limit: NA

Extinguishing Media: Chemical foam, carbon dioxide, water fog, dry chemical

Special Firefighting Procedure: None

Unusual Fire and Explosion Hazards: None

Hazardous Combustion Products: Smoke, fumes, oxides of carbon

NFPA/HMIS Codes:

Health 1

Flammability 1

Reactivity 0

Other -

8. ACCIDENTAL RELEASE MEASURES

Contain the spill, collect on absorbent material and discard as dictated by Federal, state and local regulations that may apply. Flush area thoroughly with water.

Reportable Quantity: None

9. WASTE DISPOSAL

For Used Mix: Disposal procedures must comply with local, county, state and Federal regulations. If pre-treatment is needed, ultrafiltration, emulsion breaking, or evaporation may be used. Contact CIMCOOL Technical Services at 1-513-458-8199 for assistance.

For Unused Concentrate: Concentrate is not a hazardous waste, as defined under 40 CFR 261. CIMCOOL Technical Services at 1-513-458-8199 can provide a list of waste haulers for your area.

"Empty" Containers will contain a residue which is not considered a hazardous waste under RCRA regulations. Drums can be drained to a "drip dry" condition by inversion and can be offered for recycling or scrap.

CAUTION: Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE THIS CONTAINER TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION: IT MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean drums since residue is difficult to remove. Empty drums should be completely drained, promptly bunged, and promptly returned to a drum reconditioner. Empty disposable bulk containers should be drained, sealed, and properly discarded. Empty recyclable bulk containers should be drained, sealed, and recycled. Empty pails and jugs should be drained and properly discarded.

10. HANDLING AND STORAGE

Use only as recommended by Milacron Marketing Company. Avoid all contact of concentrate with eyes or skin. Do not swallow. If frozen, thaw completely at room temperature prior to use.

Other Precautions - Product is combustible.Avoid open flames, sparks, and temperatures of 380oF or greater.

11. PHYSICAL/CHEMICAL CHARACTERISTICS

Boiling Point

NA

Evaporation Rate

Like water when diluted

Specific Gravity

0.901

Solubility in Water

Insoluble

Vapor Pressure (mm Hg)

ND

Appearance/Odor

Clear, chemical

Melting Point

ND

pH (concentrate)

NA

Vapor Density

ND

pH (NA mix)

NA

Volatile Organic Content (concentrate - by ASTM Method 2369 (Standard Test Method for Volatile Content of Coatings)): 0.00%

12. REACTIVITY

Stability: Stable

Conditions to Avoid: NA

Materials to Avoid: Avoid contact with strong acids or oxidizers to product concentrate.

Hazardous Polymerization: Will not occur.

Combustion Products: Smoke, fumes, and oxides of carbon

13. TRANSPORT INFORMATION

 

Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101):

Hazard Class

(49 CFR 172.101):

BY LAND

Not a hazardous material.

NA

BY AIR OR VESSEL (49 CFR 175-176)

NA

NA

 

U.S. Harmonized Tariff Code: 3403.99.0000

14. REGULATORY INFORMATION

EXPOSURE GUIDELINES

REGULATED MATERIAL

NIOSH REL

OSHA PEL

OSHA STEL

ACGIH TLV

ACGIH STEL

           

 

CERCLA: Components present in this product at a level which could require reporting under 40 CFR 302.4: None

EPCRA (SARA) TITLE III Extremely Hazardous Substances (302): NA

Hazardous Substances (311, 312): Product concentrate is a hazardous substance as defined under the OSHA Hazard Communication Standard and may be reportable under the provisions of SARA Sections 311 and 312.

HAZARD CATEGORIES:

Acute Health: Yes

Chronic Health: No

Fire: Yes

Sudden Release of Pressure: No

Reactive: No

 

RCRA: Product concentrate does not meet the definition of a hazardous waste as defined under 40 CFR 261 It is possible that in use, the mix may be contaminated by metals or by chlorinated solvents and the final waste may meet the TCLP definition. Each facility should assess each waste stream to determine if the used fluid should be treated as a hazardous waste.

TSCA: The ingredients of this product are on the TSCA inventory.

State Right-to-Know: Many states have enacted Community Right-To-Know laws which require information beyond that mandated by federal laws. Since some of these laws are inconsistent with the federal laws, the information in this sheet may not fully meet the requirements of every state.

 

Toxic Substances (313): Components present in the product at levels which could require reporting under the statute:

CHEMICAL NAME

CAS #

MAX. %

COMMENTS

NA

     

GLOSSARY OF ABBREVIATIONS

ACGIH

American Conference of Governmental Industrial Hygienists

CAS

Chemical Abstracts Service

CERCLA

Comprehensive Environmental Response Compensation and Liability Act

CFR

Code of Federal Regulations

COC

Cleveland Open Cup

DOT

Department of Transportation

EPCRA

Emergency Planning and Community Right-to Know Act (aka SARA)

IARC

International Agency for Research on Cancer

NA

Not Applicable

ND

Not Determined

NIOSH

National Institute of Occupational Heath and Safety

NTP

National Toxicology Program

OSHA

Occupational Safety and Health Administration

PEL

Permissible Exposure Limit

RCRA

Resource Conservation and Recovery Act

REL

Recommended Exposure Limit

SARA

Superfund Amendments and Reauthorization Act

STEL

Short-Term Exposure Limit

TCLP

Toxicity Characteristics Leaching Procedure

TLV

Threshold Limit Value

TSCA

Toxic Substances Control Act

VOC

Volatile Organic Compounds

NOTE: The opinions expressed herein are those of qualified experts within Milacron Marketing Company and of their suppliers. We believe that the information contained herein is current as of the date of this Material Data Sheet. Since the use of this information and of these opinions and the condition and use of the product are not within the control of Milacron Marketing Company, it is the user's obligation to determine the conditions of safe use of the product.

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